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NMR studies show that in model peptides, the proton is predominantly on the 2 , N 3 , or tele N in the imidazole ring, as it has a pK a 0 \)

Certain populations face higher deficiency risk: vegetarians and vegans (B12 is primarily found in animal products), adults over 50 (decreased stomach acid reduces B12 absorption), individuals with digestive disorders like Crohn's disease or celiac disease, and those taking medications like metformin or proton pump inhibitors

In particular, under metal stress, apart from the induction of GSH-based defense system (Anjum et al., 2010, 2012a