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6.1 Glutathione metabolism: modern view of biosynthetic pathways, NADPH dependence, and relationship to thioredoxin The synthesis of glutathione (GSH) predominantly occurs through the ATP-dependent -glutamyl cycle, beginning with the action of glutamate-cysteine ligase (GCL), the key rate-limiting enzyme composed of two subunits: a catalytic component (GCLC) and a regulatory modifier (GCLM)

It also supports immune function by helping white blood cells stay resilient

As GPX4 reduces phospholipid hydroperoxides, its dysfunction results in lethal lipid reactive oxygen species) ROS (accumulation ( Ferroptosis also interfaces with immune and inflammatory pathways

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