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Aug 1981;117(8):465-468

Free (unbound) lipoic acid supplements may contain either R -lipoic acid or a 50:50 (racemic) mixture of R -lipoic acid and S -lipoic acid (see Supplements)

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The link between oxidation and inflammation is complex, going from fine-tuned signaling by ROS during TLR4 activation that leads to active mobilization of damaged-associated molecular patterns, to cellular injury from redox stress that leads to damaged-associated molecular patterns release triggering TLR4-mediated inflammation and organ injury (Gill et al., 2010