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GPX4 degradation contributes to heat stress-induced liver injury via chaperone-mediated autophagy

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3 The three distinct sulphur compound classes across the vegetable kingdom glutathione, organosulphur, glucosinolates The literature describes at least three distinct families of sulphur-containing compounds across the vegetable kingdom: glutathione itself (in asparagus, avocado, spinach), the alkyl cysteine sulphoxides (in the allium family), and the glucosinolates (in the cruciferous family)

Informed by the structural data of Pt GSTF8, the accompanying mutagenesis experiments and the QM/MM studies, we investigated the impact of a disulfide bond between C13 and GSH on dehydratase activity