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Persulfides tend to be more acidic and better nucleophiles than thiols and H 2 S/HS because the anions are more available at physiological pH and have increased intrinsic reactivity due to the alpha effect, i.e., the increased reactivity of a nucleophile when the neighboring atom has high electron density ( 2 S/HS : electrophilicity (Figure 1)

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Novel insights into PARPs in gene expression: regulation of RNA metabolism

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