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The sample was subjected to LCQTOF (quadrupole time-of-flight) analysis with an Agilent 6545 QTOF equipped with a reverse-phase column (Agilent Poroshell, 120 EC-C18

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The study of the mass spectrometric fragmentation of heavy metal-biothiol conjugates has been instrumental in highlighting the key feature of thiol-bound mercury in its conjugates and is again the key to propose a more general mechanism for thiophilic glutathione-bound cations