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After the plasma membrane carrier-mediated GSH release from the cell, GSH becomes accessible to the active site of - glutamyl transpeptidase, which catalyzes the breakdown of the GSH - glutamyl bond forming two fractions: The -glutamyl fraction and the cysteinyl-glycine by transferring the -glutamyl fraction to an amino acid acceptor, forming -glutamyl-amino acid

Intact aortic rings can also break down garlic-derived organic polysulfides to release H 2 S under physiologically relevant O 2 levels

doi: 10.1038/s41419-023-05716-0 92 LingHXiaoHLuoTLinHDengJ

Tofacitinib is an immunosuppressant approved for rheumatoid arthritis