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Lets start with an acid base reaction involving a terminal alkyne (pK a 25) and acetic acid (pK a 4) [ Now lets look at water (pK a 14) and acetic acid (pK a 4) Note that each unit of difference in pK a indicates an order of magnitude difference in acidity

As described earlier and shown below, glutathione peroxidase converts hydrogen peroxide into water

Besides being the sole antioxidant enzyme able to repair lipid peroxides, GPX4 is a moonlighting protein that also regulate eicosanoid biosynthesis ( Hydroperoxides relevant to inflammation are those formed from arachidonic acid (AA) by stereoselective lipoxygenases