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Either is fine but just know that some people do experience insomnia if they take NAD too late at night, but everyone's body is different and your mileage may vary
Before Mixing: The lyophilized powder is quite stable
Nursing Mothers: Vitamin B 12 is known to be excreted in human milk
That gap is worth planning around: the beyond-use window of a reconstituted solution (covered in the storage section) can be shorter than the drug supply lasts, especially for the 10 mg vial, so re-order and reconstitution-volume decisions should be made against the shorter of the two limits the stability window or the drug supply not just the drug supply alone
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