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Alterations in gene expression profiles during prostate cancer progression: functional correlations to tumorigenicity and down-regulation of selenoprotein-P in mouse and human tumors

Although the reaction of PhSeBr and 1a generating the SeN intermediate INT1-Se is endothermic by 12.6 kcal mol 1 , INT1-Se may readily undergo a Se-centred [2,3]-sigmatropic rearrangement to generate an ortho -Se = N substituted dearomatized species ( INT2-Se ) via TS1-Se , with a barrier of 12.7 kcal mol 1

Research in the laboratory of WH is supported by Agency for Science, Technology and Research (A*STAR) Intramural funding, the Strategic Research Program (the Brain-Body Initiative, #21718), the Central Research Fund, and the JCO-VIP award

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